This comment on album openers reminded me of a fun list I read/listened to a few weeks ago. It's a bit more specific, as it pertains to the best opening tracks on debut albums. It's fairly eclectic but obviously leans towards more popular artists:
The 40 Best Debut Album Openers of All Time
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Cool list. I have always thought Caring is Creepy is a fantastic opener.
Other favorites for me:
The Doors - S/T - Break on Through (which also obviously goes with the debut albums theme)
Tom Waits - Heart of Saturday Night - New Coat of Paint
Ben Folds Five - Whatever and Ever Amen - One Angry Dwarf
Modest Mouse - Moon and Antarctica - 3rd Planet